Yellow dot is the present day ppm CO2 and the Green dot is double present ppm CO2. NASA estimates CO2 was 300 ppm in 1910 and 400 ppm in 2015. Exhibit from Coe et al. with added information.

Consensus climate science asserts as given a difference of 33°K between earth surface temperature average 288°K and top of the atmosphere temperature average 255°K. It further claims that IR active gases in the atmosphere (so-called “greenhouse gases”) cause the entire 33°K by their absorption of IR emitted from the earth.  A recent peer-reviewed paper took without challenging that presumption and proceeded to attribute the warming effect to the various GHGs:  H2O, CO2, CH4, and N2O.  The researchers are expert with measures of atmospheric radiation activity and use of the HITRAN database.  The paper is The Impact of CO2, H2O and Other “Greenhouse Gases” on Equilibrium Earth Temperatures by David Coe et al.  Excerpts in italics with my bolds.  H\T Paul Homewood

Abstract

It has long been accepted that the “greenhouse effect”, where the atmosphere readily transmits short wavelength incoming solar radiation but selectively absorbs long wavelength outgoing radiation emitted by the earth, is responsible for warming the earth from the 255K effective earth temperature, without atmospheric warming, to the current average temperature of 288K. It is also widely accepted that the two main atmospheric greenhouse gases are H2O and CO2.

What is surprising is the wide variation in the estimated warming potential of CO2, the gas held responsible for the modern concept of climate change. Estimates published by the IPCC for climate sensitivity to a doubling of CO2 concentration vary from 1.5 to 4.5°C based upon a plethora of scientific papers attempting to analyse the complexities of atmospheric thermodynamics to determine their results.

The aim of this paper is to simplify the method of achieving a figure for climate sensitivity not only for CO2, but also CH4 and N2O, which are also considered to be strong greenhouse gases, by determining just how atmospheric absorption has resulted in the current 33K warming and then extrapolating that result to calculate the expected warming due to future increases of greenhouse gas concentrations.

The HITRAN database of gaseous absorption spectra enables the absorption of earth radiation at its current temperature of 288K to be accurately determined for each individual atmospheric constituent and also for the combined absorption of the atmosphere as a whole. From this data it is concluded that H2O is responsible for 29.4K of the 33K warming, with CO2 contributing 3.3K and CH4 and N2O combined just 0.3K. Climate sensitivity to future increases in CO2 concentration is calculated to be 0.50K, including the positive feedback effects of H2O, while climate sensitivities to CH4 and N2O are almost undetectable at 0.06K and 0.08K respectively. This result strongly suggests that increasing levels of CO2 will not lead to significant changes in earth temperature and that increases in CH4 and N2O will have very little discernable impact.

Discussion

Unlike water vapour, the mean CO2 concentration will remain constant at all atmospheric levels, although its density will reduce as altitude increases and pressure and temperature decrease. CO2 concentration however will vary considerably with location and with seasons, as biospheric photosynthesis removes substantial seasonal amounts of CO2 from the atmosphere. A mean level of 400ppm has been assumed for the following calculations of atmospheric absorptivity. Similarly, CH4 and N2O concentrations will be considered to remain constant at current average levels of 1.8ppm and 0.32ppm respectively.

CH4 and N2O are indeed very powerful absorbers of infra-red radiation. Increasing the concentrations of each gas to 30ppm (a 16fold increase in the case of CH4 and an almost
100fold increase in N2O) would result in a combined absorption of 15%, close to the value of 18% for 400ppm of CO2. The combined absorptive impact in the presence of
H2O and CO2 however reduces this absorption to less than 3% as can be seen in Figure 11 due to the overlap of the absorption bands of CO2 and H2O. It would thus take a huge increase in atmospheric concentrations of these gases to have any significant impact on total atmospheric infra-red absorption.

Figures 4, 5 and 6 show the transmission of the spectral radiation Eλ, through current atmospheric concentrations of CO2 and H2O and through the combination of the two gases. Absorptivities of both CO2 and H2O, as well as CH4 and N2O, have been determined over the range 3 to 100µm to a resolution of 0.1cm-1. It is clear that significant amounts of radiated energy are absorbed by both CO2 and H2O. It is also clear that there is considerable overlap of the absorption bands of CO2 and H2O with the H2O absorption being the dominant factor.

Coe et al. Figures 4, 5 and 6.

It is of some interest to calculate the increase in temperature that has occurred due to the increase in atmospheric CO2 levels from the 280ppm prior at the start of the industrial revolution to the current 420ppm registered at the Mona Loa Observatory. (K. W. Thoning et. al. 2019) [17]. The HITRAN calculations show that atmospheric absorptivity has increased from 0.727 to 0.730 due to the increase of 140ppm CO2, resulting in a temperature increase of 0.24Kelvin. This is, therefore, the full extent of anthropogenic global warming to date.

Conclusions

From this it follows that the 33Kelvin warming of the earth from 255Kelvin, widely accepted as the zero-atmosphere earth temperature, to the current average temperature of 288Kelvin, is a 29.4K increase attributed to H2O, 3.3K to CO2 and 0.3K to CH4 and N2O combined. H2O is by far the dominant greenhouse gas, and its atmospheric concentration is determined solely by atmospheric temperature. Furthermore, the strength of the H2O infra-red absorption bands is such that the radiation within those bands is quickly absorbed in the lower atmosphere resulting in further increases in H2O concentrations having little further effect upon atmospheric absorption and hence earth temperatures. An increase in average Relative Humidity of 1% will result in a temperature increase of 0.03Kelvin.

By comparison CO2 is a bit player. It however does possess strong spectral absorption bands which, like H2O, absorb most of the radiated energy, within those bands, in the lower atmosphere. It also suffers the big disadvantage that most of its absorption bands are overlapped by those of H2O thus reducing greatly its effectiveness. In fact, the climate sensitivity to a doubling of CO2 from 400ppm to 800ppm is calculated to be 0.45 Kelvin. This increases to 0.50 Kelvin when feedback effects are taken into account. This figure is significantly lower than the IPCC claims of 1.5 to 4.5 Kelvin.

The contribution of CH4 and N2O is miniscule. Not only have they contributed a mere 0.3Kelvin to current earth temperatures, their climate sensitivities to a doubling of their present atmospheric concentrations are 0.06 and 0.08 Kelvin respectively. As with CO2 their absorption spectra are largely overlapped by the H2O spectra again substantially reducing their impact.

It is often claimed that a major contributor to global warming is the positive feedback effect of H2O. As the atmosphere warms, the atmospheric concentration of H2O also increases, resulting in a further increase in temperature suggesting that a tipping point might eventually be reached where runaway temperatures are experienced. The calculations in this paper show that this is simply not the case. There is indeed a positive feedback effect due to the presence of H2O, but this is limited to a multiplying effect of 1.183 to any temperature increase. For example, it increases the CO2 climate sensitivity from 0.45K to 0.53K.

A further feedback, however, is caused by a reduction in atmospheric absorptivity as the spectral radiance of the earth’s emitted energy increases with temperature, with peak emissions moving slightly towards lower radiation wavelengths. This causes a negative feedback with a temperature multiplier of 0.9894. This results in a total feedback multiplier of 1.124, reducing the effective CO2 climate sensitivity from 0.53 to 0.50 Kelvin.

Feedback effects play a minor role in the warming of the earth. There is, and never can be, a tipping point. As the concentrations of greenhouse gases increase, the temperature sensitivity to those increases becomes smaller and smaller. The earth’s atmosphere is a near perfect example of a stable system. It is also possible to attribute the impact of the increase in CO2 concentrations from the pre-industrial levels of 280ppm to the current 420ppm to an increase in earth mean temperature of just 0.24Kelvin, a figure entirely consistent with the calculated climate sensitivity of 0.50 Kelvin.

The atmosphere, mainly due to the beneficial characteristics and impact of H2O absorption spectra, proves to be a highly stable moderator of global temperatures. There is no impending climate emergency and CO2 is not the control parameter of global temperatures, that accolade falls to H2O. CO2 is simply the supporter of life on this planet as a result of the miracle of photosynthesis.

Footnote:

Coe et al. confirm what Ångström showed experimentally a century ago. He stated in 1900:
“Under no circumstances should carbon dioxide absorb more than 16 percent of terrestrial radiation, and the size of this absorption varies quantitatively very little, as long as there is not less than 20 percent of the existing value.”  See Pick Your A-Team: Arrhenius or Ångström

Independently, W. A. van Wijngaarden, W. Happer published findings this year similar to Coe et al. in their study Relative Potency of Greenhouse Molecules

via Science Matters

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August 31, 2021